高校化学工程学报2017，Vol.31Issue(6)：1452-1458,7.DOI:10.3969/j.issn.1003-9015.2017.06.026
等离子体强化贵金属催化净化正葵烷的研究
Study on n-Decane Removal by Plasma Assisted Noble Metal Catalysis
摘要
Abstract
A one-stage dielectric barrier discharge catalytic reaction system was used to treat simulated diesel engine exhaust gases (n-decane, C10). Effects of different noble metal catalysts on C10 removal were studied and factors of catalyst loading amount, C10 initial concentration, reaction temperature and energy density on C10 removal were discussed. The results show that comparing with only plasma or thermal catalysis, plasma catalysis can significantly improve C10 removal rates. The synergistic effect of plasma and catalyst is prominent. The catalytic performance of Pt/Al2O3 is better than that of Pd/Al2O3 and Ag/Al2O3. The conversion rate of C10 with Pd/Al2O3 is higher, and it also contributes to the oxidization of CO into CO2. The increase of catalyst loading amount, energy density and reaction temperature can improve removal rates and COx selectivity of C10. The maximum removal rate is up to 91% and the highest COx selectivity is 54.3%. The increase of C10 initial concentration is not helpful to C10 removal.关键词
介质阻挡放电/贵金属催化剂/C10/去除率/COx选择性Key words
dielectric barrier discharge/noble metal catalyst/n-decane/removal rate/COx selectivity分类
化学化工引用本文复制引用
吴祖良,朱周彬,章旭明,郝晓东,叶静静,姚水良..等离子体强化贵金属催化净化正葵烷的研究[J].高校化学工程学报,2017,31(6):1452-1458,7.基金项目
浙江省公益性研究项目(2017C33042) （2017C33042）
国家自然科学基金(11575159). （11575159）
