火炸药学报2017，Vol.40Issue(6)：55-58,4.DOI:10.14077/j.issn.1007-7812.2017.06.009
铬杂氮团簇CrN+n的生成及光解
Formation and Photodissociation of Cr-doped Nitrogen Clusters CrN +n
摘要
Abstract
The substrate with a diameter of 13mm and thickness of 2 - 5 mm was prepared by compressing Cr /boron nitride (BN) mixed powder using a pressing tablet mechine ,and then on a reflection type flight time mass spectrom-eter ,using high purity N2 as carrier gas ,the Cr/BN substrate was ablated with the laser ,the Cr-doped nitrogen clusters CrN +n (n= 2 ,4 ,6 ,8) were generated and its mass spectrogram was obtained .The photodissociation of CrN +6 and CrN +8 was performed by laser with a wavelength of 266 nm ,its photodissociation spectrogram was obtained ,and the compositions of Cr-doped nitrogen clusters were discussed .The results show that in generated Cr-doped nitrogen clusters CrN +n ,CrN +8 is more stable ,which are composed in a difference of two nitrogen atoms in turn ,predicting that CrN +8 is composed of Cr + and N2 .关键词
氮团簇/铬杂氮团簇/激光溅射/光解/高能量密度材料Key words
nitrogen cluster/Cr-doped nitrogen clusters/laser ablation/photodissociation/high energy density material分类
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李陶琦,丁可伟,许洪光,卜建华,肖啸,郑卫军,葛忠学..铬杂氮团簇CrN+n的生成及光解[J].火炸药学报,2017,40(6):55-58,4.基金项目
装备发展部重大专项 （）
