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碱性木质素对玉米秸秆成型特性的影响

李伟振 姜洋 饶曙 阴秀丽 蒋恩臣

林产化学与工业2017,Vol.37Issue(6):35-42,8.
林产化学与工业2017,Vol.37Issue(6):35-42,8.DOI:10.3969/j.issn.0253-2417.2017.06.005

碱性木质素对玉米秸秆成型特性的影响

Effect of Alkali Lignin on Corn Stalk Pelleting Process

李伟振 1姜洋 2饶曙 3阴秀丽 4蒋恩臣2

作者信息

  • 1. 中国科学院广州能源研究所,广东广州510640
  • 2. 中国科学院可再生能源重点实验室,广东广州510640
  • 3. 广东省新能源和可再生能源研究开发与应用重点实验室,广东广州510640
  • 4. 中国科学院广州能源研究所,广东广州510640
  • 折叠

摘要

Abstract

In order to study the effect of alkali lignin on corn stalk pelleting process and the bonding mechanism, the influences of four parameters ( alkali lignin adding amount, temperature, moisture and pressure ) on three technical indicators ( relaxed density, radial compressive strength and specific energy consumption) were investigated. The compression molding experiment showed that when alkali lignin adding amount increased from 0 to 20%, the relaxed density of corn stalk pellets increased from 1005 kg/m3 to 1157 kg/m3 and the radial compressive strength increased from 1353 N to 1930 N. This results suggested that increasing of alkali lignin could promote the corn stalk pelleting process. The thermal transition temperatures of corn stalk and alkali lignin were also studied by differential scanning calorimetry ( DSC ) . The results showed that the glass transition temperatures of corn straw and alkali lignin were between 92. 5-103 ℃ and 61-137 ℃, respectively. In the thermal transition temperature range, 100 ℃ was the lowest specific energy consumption with suitable moisture content. The suitable temperature range for alkali lignin bonding was 100-130℃. The microstructure of pellets showed that alkali lignin occurred melting transition after melting temperature and then formed'molten combination' and'mechanical interlocking' inside the particles. The suitable alkali lignin adding amount for bonding was 10% -15%.

关键词

压缩成型/碱性木质素/黏结机理/比能耗/热转变温度/微观形态

Key words

pelleting/alkali lignin/bonding mechanism/specific energy consumption/thermal transition/microstructure

分类

化学化工

引用本文复制引用

李伟振,姜洋,饶曙,阴秀丽,蒋恩臣..碱性木质素对玉米秸秆成型特性的影响[J].林产化学与工业,2017,37(6):35-42,8.

基金项目

国家自然科学基金资助项目(51661145022) (51661145022)

广东省科技计划项目(2017A010104009) (2017A010104009)

广州市科技计划项目(201704020189) (201704020189)

林产化学与工业

OA北大核心CSCDCSTPCD

0253-2417

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