日用化学工业2017，Vol.47Issue(12)：673-676,4.DOI:10.13218/j.cnki.csdc.2017.12.003
水热辅助相转移催化水解十二烷基苄氯的研究
Investigation for hydrolysis of dodecylbenzyl chloride by hydrothermal-assisted phase transfer catalysis
摘要
Abstract
Hydrolysis of n-dodecylbenzyl chloride was preliminarily tested separately by means of ultrasonic wave,microwave,hydrothermal and phase transfer catalysis,and finally the hydrothermal - assisted phase transfer catalysis succeeded. Based upon the test results,the conclusion is to use dodecyldimethylbenzyl-ammonium chloride as the phase transfer catalyst and the reaction is conducted under alkaline condition with hydrothermal assistance at 130 ℃ for 16 h. The yield achieves 93. 6%.关键词
十二烷基苄氯/水解/水热/相转移催化Key words
dodecylbenzyl chloride/hydrolysis/hydrothermal/phase transfer catalysis分类
化学化工引用本文复制引用
孙美玲,胡学一,方云,方银军..水热辅助相转移催化水解十二烷基苄氯的研究[J].日用化学工业,2017,47(12):673-676,4.基金项目
国家重点研发项目(2017YFB03080900) （2017YFB03080900）
赞宇科研基金资助项目 （）
