天然气化工2017,Vol.42Issue(6):44-45,85,3.
制备工艺对Mo/HZSM-5催化剂甲烷脱氢芳构化性能的影响
Effects of preparation methods on performance of Mo/HZSM-5 catalysts for methane dehydro-aromatization
摘要
Abstract
The Mo/HZSM-5 catalysts were prepared by three different room temperature methods, impregnation-suction filtration, impregnation-rotary evaporation and ball milling-impregnation, and the properties of methane aromatization on the catalysts were investigated in a fluidized bed reactor. The results showed that compared with the impregnation-suction filtration method, the impregnation-rotary evaporation and ball milling-impregnation methods provided higher Mo loadings, and the catalysts prepared by the two methods exhibited higher methane conversion (16%- 19% and 18%-21%, respectively), total aromatics selectivity (85% and 83%, respectively) and lower wear index (0.71%/h and 0.85%/h, respectively).关键词
催化剂/HZSM-5分子筛/制备工艺/甲烷/芳构化Key words
catalyst/HZSM-5 zeolite/preparation method/methane/aromatization分类
化学引用本文复制引用
张华,张伟..制备工艺对Mo/HZSM-5催化剂甲烷脱氢芳构化性能的影响[J].天然气化工,2017,42(6):44-45,85,3.基金项目
陕西延长石油(集团)有限责任公司"308科研攻关项目研究"(ycsy2013ky-A-15) (集团)