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不同导电添加剂对SiO/C锂离子电池性能的影响

滕鑫 许洪亮 刘琦 石丽丽 盖亮 王垒 杨裕生 吴锋

新型炭材料2017,Vol.32Issue(6):572-580,9.
新型炭材料2017,Vol.32Issue(6):572-580,9.DOI:10.1016/S1872-5805(17)60138-0

不同导电添加剂对SiO/C锂离子电池性能的影响

The influence of conductive additives on the performance of a SiO/C composite anode in lithium-ion batteries

滕鑫 1许洪亮 1刘琦 1石丽丽 1盖亮 1王垒 1杨裕生 1吴锋1

作者信息

  • 1. 北京理工大学 材料学院,北京 100081
  • 折叠

摘要

Abstract

Two conductive additives, carbon black (Super-P) and vapor-grown carbon fibers (VGCFs), were used in 2. 5 Ah Li ion batteries using LiCoO2 as the cathode and a SiO/C composite as the anode. The electrode shape, peel strength, electrolyte ab-sorption, electrolyte storage capacity, volume change and the electrochemical performance were investigated. Results indicate that both batteries have high energy densities ( more than 600 Wh/L) , but the batteries with VGCFs have the better low temperature per-formance, longer cycle life, higher rate capability and lower volume expansion, which is ascribed to the superior conductive network formed by the VGCFs.

关键词

SiO/C负极锂离子电池/VGCF/倍率性能/循环寿命

Key words

SiO/C anode Lithium-ion battery/VGCF/Rate capabilities/Cycle life

分类

化学化工

引用本文复制引用

滕鑫,许洪亮,刘琦,石丽丽,盖亮,王垒,杨裕生,吴锋..不同导电添加剂对SiO/C锂离子电池性能的影响[J].新型炭材料,2017,32(6):572-580,9.

基金项目

教育部"新世纪优秀人才支持计划" (NCET-12-0047) (NCET-12-0047)

国家重点基础研究"973"计划项目(2015CB251100) (2015CB251100)

北京高等院校能源电池和化学能源材料工程研究中心项目. Program for New Century Excellent Talents in University (NCET-12-0047) (NCET-12-0047)

National Basic Research Program of China (2015CB251100) (2015CB251100)

Program of Beijing Higher Institution Engineering Research Center of Power Battery and Chemical Energy Materials. ()

新型炭材料

OA北大核心CSCDCSTPCD

1007-8827

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