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废弃粉末活性炭热解再生实验及表征分析

路遥 李建芬 李红霞 辛馨 史训旺 刘照 程群鹏

化工进展2018,Vol.37Issue(1):389-394,6.
化工进展2018,Vol.37Issue(1):389-394,6.DOI:10.16085/j.issn.1000-6613.2017-0816

废弃粉末活性炭热解再生实验及表征分析

Experimental and characteristic analysis on pyrolysis regeneration of waste powdered activated carbon

路遥 1李建芬 1李红霞 1辛馨 1史训旺 1刘照 1程群鹏1

作者信息

  • 1. 武汉轻工大学化学与环境工程学院,湖北 武汉 430023
  • 折叠

摘要

Abstract

The effect of pyrolysis regeneration on the specific surface area,pore structure and the decomposition of organic matter of waste powdered activated carbon(WPAC)was studied through X-ray diffraction(XRD),Fourier transform infrared analysis(FTIR),BET and thermo-gravimetric analysis(TG). Meanwhile,the adsorption capacity of waste powdered activated carbon were analyzed before and after pyrolysis. The optimal pyrolysis conditions as follow:N2as carrier gas,the regeneration temperature and the time of pyrolysis is 650℃ and 2h respectively. Under this condition, BET surface area of RPAC could be recovered to 1161.4m2/g which was 94.5% of fresh activated carbon. Langmuir model could well describe the adsorption isotherm of methylene Blue. The adsorption capacity of RPAC for the methylene blue was 420.5mg/g which was 89.6% of fresh activated carbon. The results showed that the surface chemical property,pore structure of WPAC and adsorption capacity could be effectively recovered through pyrolysis.

关键词

活性炭/热解/再生/比表面积

Key words

activated carbon/pyrolysis/regeneration/specific surface area

分类

化学化工

引用本文复制引用

路遥,李建芬,李红霞,辛馨,史训旺,刘照,程群鹏..废弃粉末活性炭热解再生实验及表征分析[J].化工进展,2018,37(1):389-394,6.

基金项目

国家农业科技专项(201503135)、湖北省高校优秀科技团队计划(T201407)及湖北省科技支撑计划(2014BAA110)项目. (201503135)

化工进展

OA北大核心CSCDCSTPCD

1000-6613

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