化工进展2018,Vol.37Issue(1):389-394,6.DOI:10.16085/j.issn.1000-6613.2017-0816
废弃粉末活性炭热解再生实验及表征分析
Experimental and characteristic analysis on pyrolysis regeneration of waste powdered activated carbon
摘要
Abstract
The effect of pyrolysis regeneration on the specific surface area,pore structure and the decomposition of organic matter of waste powdered activated carbon(WPAC)was studied through X-ray diffraction(XRD),Fourier transform infrared analysis(FTIR),BET and thermo-gravimetric analysis(TG). Meanwhile,the adsorption capacity of waste powdered activated carbon were analyzed before and after pyrolysis. The optimal pyrolysis conditions as follow:N2as carrier gas,the regeneration temperature and the time of pyrolysis is 650℃ and 2h respectively. Under this condition, BET surface area of RPAC could be recovered to 1161.4m2/g which was 94.5% of fresh activated carbon. Langmuir model could well describe the adsorption isotherm of methylene Blue. The adsorption capacity of RPAC for the methylene blue was 420.5mg/g which was 89.6% of fresh activated carbon. The results showed that the surface chemical property,pore structure of WPAC and adsorption capacity could be effectively recovered through pyrolysis.关键词
活性炭/热解/再生/比表面积Key words
activated carbon/pyrolysis/regeneration/specific surface area分类
化学化工引用本文复制引用
路遥,李建芬,李红霞,辛馨,史训旺,刘照,程群鹏..废弃粉末活性炭热解再生实验及表征分析[J].化工进展,2018,37(1):389-394,6.基金项目
国家农业科技专项(201503135)、湖北省高校优秀科技团队计划(T201407)及湖北省科技支撑计划(2014BAA110)项目. (201503135)