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典型含锑物料的湿法分离锑研究

徐亚飞 冯攀 俞小花 李永刚 俞双林 谢刚

矿产综合利用Issue(6):31-35,5.
矿产综合利用Issue(6):31-35,5.DOI:10.3969/j.issn.1000-6532.2017.06.007

典型含锑物料的湿法分离锑研究

Study on the Separation of Antimony by Hydrometallurgy with Typical Material Containing Sb

徐亚飞 1冯攀 2俞小花 2李永刚 1俞双林 2谢刚1

作者信息

  • 1. 云南冶金集团创能金属燃料电池股份有限公司,650500,云南 昆明
  • 2. 昆明理工大学冶金与能源工程学院,云南 昆明,650093
  • 折叠

摘要

Abstract

With the continuous depletion of antimony resources,antimony is a valuable strategic resource for a country.Antimony recovery must be paid attention to,and the efficient using of antimony material is the first,and dealing with this materials is the key to recovery antimony or its compounds from them.This paper introduced several methods for the separation of antimony by hydrometallurgy with typical material containing Sb.A large number of research results were reviewed,summarizing material leaching of antimony is generally alkaline leaching.Oxidation is easy to occur under alkaline conditions,which often combined with oxidant Sb3+oxidation into Sb5+.It is pointed out that the pressure can improve the leaching rate of antimony.When Na2S is added into the alkaline solution,antimony can be precipitated to form sodium antimony to recover antimony.By processing for the separation and extraction of antimony from antimony containing materials,it is concluded that the wet treatment of the material containing antimony has the advantages of high recovery rate,easy separation of antimony and other materials,friendly environment,low cost and low equipment requirements.Antimony containing materials are often associated with other valuable metals:arsenic,bismuth,lead,gold,silver,copper,iron,etc..These metals are recovered by leaching residue or leaching solution,which can not only achieve the recovery of antimony,but also other valuable metals.The wet treatment of antimony containing materials will gradually replace the fire method,and more and more attention has been paid to the wet treatment of antimony containing materials.

关键词

湿法/碱性/氧化浸出/

Key words

Hydrometallurgy/Alkaline/Oxidizing leaching/Antimony

分类

矿业与冶金

引用本文复制引用

徐亚飞,冯攀,俞小花,李永刚,俞双林,谢刚..典型含锑物料的湿法分离锑研究[J].矿产综合利用,2017,(6):31-35,5.

基金项目

国家自然科学基金面上项目(No.51374118),共伴生有色金属资源加压湿法冶金技术国家重点实验室开放基金(yy2016003) (No.51374118)

矿产综合利用

OA北大核心CSTPCD

1000-6532

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