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凝胶色谱法测定超高相对分子质量聚乙烯的 相对分子质量及其分布

郭宁 盛亮 陈成鑫 史清军 唐颂超 郑安呐

石油化工2017,Vol.46Issue(11):1424-1427,4.
石油化工2017,Vol.46Issue(11):1424-1427,4.DOI:10.3969/j.issn.1000-8144.2017.11.014

凝胶色谱法测定超高相对分子质量聚乙烯的 相对分子质量及其分布

Determination of molecular weight and its distribution of ultrahigh molecular weight polyethylene by gel chromatography

郭宁 1盛亮 2陈成鑫 3史清军 3唐颂超 3郑安呐1

作者信息

  • 1. 华东理工大学 材料科学与工程学院,上海 200237
  • 2. 上海化工研究院有限公司 聚烯烃催化技术与高性能材料国家重点实验室,上海 200062
  • 3. 北京亿路达机电设备有限公司,北京 100081
  • 折叠

摘要

Abstract

With special IR5-MCT detector and GPC type rapid column,the new gel chromatography GPC-IR was used to get the molecular weight and its distribution of ultra high molecular weight polyethylene. The molecular weight and its distribution of three kinds of ultra high molecular weight polyethylene were characterized. The experimental results show that the new type of gel chromatography can be used for quantitative determination of extremely dilute the sample solution. The results have a high accuracy,good repeatability and fully meet the requirements of quantitative analysis. The new GPC-IR overcome the traditional high temperature GPC shortcoming that can not analyze the problem of ultra high molecular weight polyethylene.

关键词

超高相对分子质量聚乙烯/相对分子质量/相对分子质量分布

Key words

Ultra-high molecular weight polyethylene/molecular weight/molecular weight distribution

分类

化学化工

引用本文复制引用

郭宁,盛亮,陈成鑫,史清军,唐颂超,郑安呐..凝胶色谱法测定超高相对分子质量聚乙烯的 相对分子质量及其分布[J].石油化工,2017,46(11):1424-1427,4.

石油化工

OA北大核心CSCDCSTPCD

1000-8144

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