物理化学学报2017，Vol.33Issue(11)：2173-2183,11.DOI:10.3866/PKU.WHXB201705312
纳米受限水的研究进展
Research Progress of Nanoconfined Water
摘要
Abstract
Water is an indispensable resource for all biological life on earth.It is crucial for the existence of human beings and civilizations have historically thrived around water bodies.However,there still remains an enormous cognitive gap about the abnormal properties of water,its influence in the field of physics,chemistry,and biology,and the underlying mechanism of its effect on natural processes.Hydroscience has gradually entered the arena for scientific discussion and transformed into a main research area.While the majority of water on earth exists as bulk water,it typically participates in different physical and chemical processes in the form of interface/confined water under both natural and scientific research conditions.Nanoconfined water generally exists in natural and synthetic nanoscale environments,and its distinction from bulk water is mainly reflected in its dynamic and thermodynamic properties.The existence of confined water also has a profound impact on the development of devices composed of nanomaterials and their applications in the fields of biology,environmental science,geology etc.In this paper,the hydrogen bond structure of nanoconflned water has been analyzed and its dynamic,thermodynamic,and electrical properties have been generalized.A summary of the different research methods and their corresponding developmental history,together with examples of the application potential of nanoconfined water in the fields of environmental and material science have been presented.A summary of the progress made and existing problems in the research area of confined water is given along with the prospects for future developments.关键词
纳米受限水/氢键/动力学/相变/分子动力学模拟Key words
Nanoconfined water/Hydrogen bond/Dynamics/Phase transition/Molecular dynamics simulation分类
化学化工引用本文复制引用
孙怡然,于飞,马杰..纳米受限水的研究进展[J].物理化学学报,2017,33(11):2173-2183,11.基金项目
The project was supported by the National Natural Science Foundation of China (21577099,51408362) and Natural Science Foundation of Jiangsu Province,China (BK20151300).国家自然科学基金(21577099,51408362)和江苏省自然科学基金(BK20151300)资助项目 （21577099,51408362）
