物理化学学报2017，Vol.33Issue(12)：2550-2558,9.DOI:10.3866/PKU.WHXB201706071
固相聚合合成聚噻吩衍生物及烷基链对固相聚合的影响
Synthesis of Poly(bis-3,4-ethylenedioxythiophene methine)s with Side-Chain Comprising Electro-Optical Moieties and Alkyl Chain Effect in Solid State Polymerization
摘要
Abstract
New poly(bis-3,4-ethylenedioxythiophene methine)s derivatives with typical electro-optical moieties of thiophene, carbazole and fluorene as the side chains are obtained by facile solid state polymerization (SSP) or melt state polymerization (MSP). Detail characterizations of these polymers are carried out and some key monomers' crystals are obtained for structures analysis. It is found that existence of alkyl chains decrease monomers onset temperatures for SSP (Tonset) due to the weakening of the intermolecular interaction in crystals.关键词
聚噻吩衍生物/固相/熔融聚合/烷基链影响Key words
Poly(bis-3/4-ethylenedioxythiophene methine)s derivatives/Solid and melt state polymerization/Alkyl chain effect分类
化学化工引用本文复制引用
裴童,彭凯,蔡心怡,袁良杰,夏江滨..固相聚合合成聚噻吩衍生物及烷基链对固相聚合的影响[J].物理化学学报,2017,33(12):2550-2558,9.基金项目
The project was supported by the National Natural Science Foundation of China (21371138), the Funds for Creative Research Groups of Hubei Province, China (2014CFA007) and the Fundamental Research Funds for the Central Universities, China (2042015kf0180). 国家自然科学基金(21371138),湖北省创新团队科研基金(2014CFA007)及中央高校基本科研业务费专项资金(2042015kf0180)资助项目 （21371138）
