物理化学学报2018，Vol.34Issue(1)：36-48,13.DOI:10.3866/PKU.WHXB201706304
ZnO电极修饰层在钙钛矿太阳能电池中的应用
Application of ZnO Electrode Buffer Layer in Perovskite Solar Cells
摘要
Abstract
ZnO has attracted extensive research in perovskite solar cells because of its high electron mobility,spectacular optical transparency, low-temperature processing, and ease of synthesis. Traditional electrode buffer layers used in perovskite solar cells have shown some drawbacks, such as high-temperature treatment, low transmittance, and complex fabrication procedures, which might not be fit for the further development of high-performance flexible perovskite solar cells. Here, we intend to give a systematic introduction to the fabrication and functions of ZnO electrode buffer layers (sol-gel method, pre-fabricated ZnO nanoparticle suspension, atomic layer deposition, spray pyrolysis, electrodeposition,chemical bath deposition, radio-frequency sputtering, metal organic chemical vapor deposition, and magnetron sputtering etc.). Particular attentions were paid to the understanding of the structure-property relations between the thickness,morphology, doping, and composition of ZnO electrode buffer layers and the performance of perovskite solar cells (open circuit voltage, current density, fill factor, power conversion efficiency, etc.). A perspective on the future development of ZnO electrode buffer layers and their applications in perovskite solar cells were also discussed in this review.关键词
钙钛矿电池/ZnO电极修饰层/掺杂/复合/光电转换效率Key words
Perovskite solar cells/ZnO electrode buffer layer/Doping/Composition/Photoelectric conversion efficiency分类
化学化工引用本文复制引用
许利刚,邱伟,陈润锋,张宏梅,黄维..ZnO电极修饰层在钙钛矿太阳能电池中的应用[J].物理化学学报,2018,34(1):36-48,13.基金项目
The project was supported by the National Key Basic Research Program of China (973) (2015CB932203), National Natural Science Foundation of China (61604079, 21674049), the Initiative Postdocs Supporting Program, China (BX201600076), China Postdoctoral Science Foundation (2017M611879), Scientific Starting Fund from Nanjing University of Posts and Telecommunications, China (NY215015)国家重点基础研究发展规划项目(973 计划) (2015CB932203),国家自然科学基金(61604079, 21674049),博士后创新人才计划(BX201600076),中国博士后科学基金(2017M611879)和南京邮电大学科研启动基金(NY215015)资助 （973）
