硅酸盐通报2017，Vol.36Issue(12)：4183-4187,5.
FeCl3/石墨插层化合物的制备及储锂性能研究
Preparation and Lithium Storage Properties of Graphite Intercalation Compound
黄振萍 1王竹锟 2吴正颖 2李晓伟3
作者信息
- 1. 南通师范高等专科学校数理系,南通 226016
- 2. 苏州科技大学化学生物与材料工程学院,苏州 215009
- 3. 苏州大学物理与光电·能源学部,苏州 215006
- 折叠
摘要
Abstract
A stage 2 ferric chloride-graphite intercalation compound (FeCl3-GIC) was prepared by the technology of intercalation using metal chloride and graphite flake as raw materials .The structure and lithium storage properties of the FeCl 3-GIC compound were investigated by infrared spectrometer , X-ray diffraction , Raman spectrometer , and galvonastatic charge/discharge test .The results show that partial FeCl3 has been transferred to Fe 2 O3 during the preparation of FeCl 3-GIC.The FeCl3-GIC with expanded interlayer spacing exhibits a high initial capacity of 1220 mAh/g at a current density of 50 mA/g. Furthermore, FeCl3-GIC still remains a capacity of 355 mAh/g after 100 cycles at a current density of 200 mA/g.Therefore, the good lithium storage properties make FeCl 3-GIC promising as an anode material for lithium ion batteries .关键词
氯化铁/石墨/插层化合物/储锂性能Key words
FeCl3/graphite/GIC/lithium storage分类
信息技术与安全科学引用本文复制引用
黄振萍,王竹锟,吴正颖,李晓伟..FeCl3/石墨插层化合物的制备及储锂性能研究[J].硅酸盐通报,2017,36(12):4183-4187,5.
