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磷酸盐结合法制备Al2O3多孔陶瓷及性能

冯鑫 刘涛 黎阳

人工晶体学报2017,Vol.46Issue(12):2332-2336,5.
人工晶体学报2017,Vol.46Issue(12):2332-2336,5.

磷酸盐结合法制备Al2O3多孔陶瓷及性能

Preparation and Properties of Porous Alumina Ceramics by Phosphate Bonding Method

冯鑫 1刘涛 1黎阳1

作者信息

  • 1. 贵州师范大学材料与建筑工程学院,贵阳550018
  • 折叠

摘要

Abstract

Porous alumina ceramics were prepared by methods of compression molding , drying and sintering with calcined α-Al2 O3 powder as aggregate , aluminum dihydrogen phosphate as binder and paraffin as molding promoter .The effect of sintering temperature and aluminum dihydrogen phosphate content on microstructure , phase composition , linear shrinkage , porosity and flexural strength were studied.The mechanisms of sintering by phosphate bonding method were discussed .Results show that the phase compositions of porous alumina ceramics are α-Al2 O3 and AlPO4 .Porous alumina ceramics are formed by AlPO4 bonding among alumina particles at low temperature .With increasing aluminum dihydrogen phosphate content , the linear shrinkage and flexural strength increase smoothly , while the porosity decrease .The existence of AlPO 4 accelerates the liquid-phase sintering among the alumina particles at high temperature .The linear shrinkage and flexural strength increase sharply with increasing sintering temperature , and the porosity decrease obviously .

关键词

磷酸二氢铝/氧化铝/磷酸盐结合法/多孔陶瓷/磷酸铝

Key words

aluminum dihydrogen phosphate/alumina/phosphate bonding method/porous ceramics/aluminum phosphate

分类

化学化工

引用本文复制引用

冯鑫,刘涛,黎阳..磷酸盐结合法制备Al2O3多孔陶瓷及性能[J].人工晶体学报,2017,46(12):2332-2336,5.

基金项目

贵州省教育厅自然科学研究项目([2015]363) ([2015]363)

国家自然科学基金(51462004) (51462004)

人工晶体学报

OA北大核心CSCDCSTPCD

1000-985X

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