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In、Gd共掺对BaCeO3基质子导体性能的影响

马欣宇 杨春利 严敏 吕强 陈红

人工晶体学报2017,Vol.46Issue(12):2380-2385,6.
人工晶体学报2017,Vol.46Issue(12):2380-2385,6.

In、Gd共掺对BaCeO3基质子导体性能的影响

Effect of In, Gd Co-doping on the Performance of BaCeO3-based Proton Conductor

马欣宇 1杨春利 1严敏 1吕强 1陈红1

作者信息

  • 1. 西安建筑科技大学材料与矿资学院功能材料研究所,西安 710055
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摘要

Abstract

High temperature proton conductors were widely studied , because of their using in fuel cell , hydrogen separation membrane and hydrogen sensor , etc.In this paper, In and Gd co-doped BaCeO3 proton conductors were prepared by modified citrate method .The microstructure , chemical stability and electrical conductivity were further studied .The results show that the basicity of the system is improved after doping due to the low electronegativity of Gd , which leads to poor chemical stability .However , the ion radius of Gd is smaller than that of Ce , which is more favorable for ion transportation .Therefore , Gd single-doping and In , Gd co-doping samples have higher conductivity than traditional proton conductor samples.

关键词

质子导体/掺杂的BaCeO3/化学稳定性/烧结活性

Key words

proton conductor/doped BaCeO 3/chemical stability/sinterability

分类

通用工业技术

引用本文复制引用

马欣宇,杨春利,严敏,吕强,陈红..In、Gd共掺对BaCeO3基质子导体性能的影响[J].人工晶体学报,2017,46(12):2380-2385,6.

基金项目

国家自然科学青年基金(21506168) (21506168)

西安建筑科技大学人才科技基金(RC1251) (RC1251)

人工晶体学报

OA北大核心CSCDCSTPCD

1000-985X

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