人工晶体学报2017,Vol.46Issue(12):2380-2385,6.
In、Gd共掺对BaCeO3基质子导体性能的影响
Effect of In, Gd Co-doping on the Performance of BaCeO3-based Proton Conductor
摘要
Abstract
High temperature proton conductors were widely studied , because of their using in fuel cell , hydrogen separation membrane and hydrogen sensor , etc.In this paper, In and Gd co-doped BaCeO3 proton conductors were prepared by modified citrate method .The microstructure , chemical stability and electrical conductivity were further studied .The results show that the basicity of the system is improved after doping due to the low electronegativity of Gd , which leads to poor chemical stability .However , the ion radius of Gd is smaller than that of Ce , which is more favorable for ion transportation .Therefore , Gd single-doping and In , Gd co-doping samples have higher conductivity than traditional proton conductor samples.关键词
质子导体/掺杂的BaCeO3/化学稳定性/烧结活性Key words
proton conductor/doped BaCeO 3/chemical stability/sinterability分类
通用工业技术引用本文复制引用
马欣宇,杨春利,严敏,吕强,陈红..In、Gd共掺对BaCeO3基质子导体性能的影响[J].人工晶体学报,2017,46(12):2380-2385,6.基金项目
国家自然科学青年基金(21506168) (21506168)
西安建筑科技大学人才科技基金(RC1251) (RC1251)