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过氧化氢漂白富纤维素材料制备透明纤维素膜研究

王丽莉 欧阳土龙 戴兴兴 卢兴庚 梁华珍 邓榕 程芳超

森林工程2018,Vol.34Issue(1):41-45,59,6.
森林工程2018,Vol.34Issue(1):41-45,59,6.

过氧化氢漂白富纤维素材料制备透明纤维素膜研究

Preparation of Transparent Cellulose Membrane by Hydrogen Peroxide Bleaching of Cellulose-Rich Materials

王丽莉 1欧阳土龙 1戴兴兴 1卢兴庚 1梁华珍 1邓榕 1程芳超1

作者信息

  • 1. 广西大学 林学院, 广西壮族自治区 南宁 530004
  • 折叠

摘要

Abstract

To fractionate biomass and prepare transparent cellulose membrane , bagasse and poplar , as raw biomass materials , were extracted by benzene-alcohol solution and then fractionated with ionic liquid system .The obtained cellulose-rich material(CRM) was bleached by alkaline hydrogen peroxide solution .Three-factor mixed level orthogonal experiments were designed to optimize the bleaching process , and the differences on CIE L*a*b* colorimetry parameters of CRMs before and after the bleaching process were analyzed.Finally, transparent cellulose membranes were produced by ultrasound treatment of bleached bagasse CRM .Results indica-ted that hydrogen peroxide had obvious effects on bleaching and delignification of CRM , and the bleaching effect of the system on ba-gasse CRM was significantly higher than that of poplar CRM .The optimal bleaching conditions were as follows: the reaction tempera-ture was 75 ℃, the concentration of hydrogen peroxide was 15% and the reaction time was 1 h.The reaction temperature had the greatest effect on the experimental results .Bleached CRM can be used to produce transparent cellulose membrane through further ultra -sonic process .

关键词

富纤维素材料/过氧化氢/漂白/离子液体/透明纤维素膜

Key words

Cellulose-rich material/hydrogen peroxide/bleaching/ionic liquid/transparent cellulose membranes

分类

轻工纺织

引用本文复制引用

王丽莉,欧阳土龙,戴兴兴,卢兴庚,梁华珍,邓榕,程芳超..过氧化氢漂白富纤维素材料制备透明纤维素膜研究[J].森林工程,2018,34(1):41-45,59,6.

基金项目

国家自然科学基金(31760183) (31760183)

广西自然科学基金回国基金项目(2016GXNSFCA380025) (2016GXNSFCA380025)

广西大学科研基金资助项目(XGZ150513) (XGZ150513)

广西大学大学生创新创业训练计划(201610593273) (201610593273)

森林工程

OACSTPCD

1006-8023

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