应用化学2018，Vol.35Issue(1)：1-20,20.DOI:10.11944/j.issn.1000-0518.2018.01.170328
激发态分子内质子转移荧光探针的研究进展
Advanced in Fluorescent Probes Based on Excited State Intramolecular Proton Transfer
摘要
Abstract
Fluorescent probes are gaining more and more attention because of their high selectivity , sensitivity , fast response , simple operation and low detection limit .Compounds based on excited state intramolecular proton transfer( ESIPT) have special excited state photophysical properties , such as high fluorescence quantum yield and large Stokes shift .For fluorescent molecules , the larger Stokes shift can reduce the interference caused by self-absorption and internal filtration , and enhance light-fastness of the molecules and facilitate the emitting of fluorescence .In this review , we summarized these ESIPT fluorescent probes from the classification of targets.The targets for detection were divided into ions ( including metal cations and anions ) , neutral small molecules and biological macromolecules .The existing problems and application prospects of fluorescent molecules based on ESIPT were commented .关键词
激发态分子内质子转移/金属阳离子/阴离子/中性小分子/生物大分子/荧光探针Key words
sexcited state intramolecular proton transfer/metal cations/anions/neutral small molecule/biological macromolecule/fluorescence probes分类
化学化工引用本文复制引用
王德佳,徐勇前,孙世国,李红娟..激发态分子内质子转移荧光探针的研究进展[J].应用化学,2018,35(1):1-20,20.基金项目
国家自然科学基金资助项目(21676218,21476185,21472016,21272030) Supported by the National Natural Science Foundation of China(No.21676218, No.21476185,21472016, No.21272030) （21676218,21476185,21472016,21272030）
