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近红外聚乙烯醇荧光高分子材料的制备及性能

孙琪 王丽秋 刘洋 郭晨晓 王鹏君 刘学龙 张晓博 郑立辉 刘丽萍

应用化学2018,Vol.35Issue(1):53-59,7.
应用化学2018,Vol.35Issue(1):53-59,7.DOI:10.11944/j.issn.1000-0518.2018.01.170344

近红外聚乙烯醇荧光高分子材料的制备及性能

Preparation and Properties of Near Infrared Polyvinyl Alcohol Fluorescent Polymer Materials

孙琪 1王丽秋 2刘洋 1郭晨晓 1王鹏君 1刘学龙 1张晓博 1郑立辉 1刘丽萍1

作者信息

  • 1. 燕山大学环境与化学工程学院 河北秦皇岛066004
  • 2. 江西晶安高科技股份有限公司 南昌330508
  • 折叠

摘要

Abstract

Near-infrared fluorescence squaraine/polyvinyl alcohol ( PVA ) binary and squaraine/hydrophilic graphene/PVA ternary polymers with stronger fluorescence ( 660 ~665 nm ) intensity , photostability and thermostability were designed and synthesized from a squaraine dye , water soluble graphene and PVA . Compared to those in water , the maximum UV-Vis absorption and fluorescence wavelengths of the squaraine in PVA showed red shifts , and the fluorescence intensity and photostability were significantly enhanced .The presence of the graphene improved the photostability and thermostability of the material .

关键词

近红外荧光高分子材料/聚乙烯醇/改性与合成/方酸菁染料/石墨烯

Key words

near infrared fluorescence polymer materials/polyvinyl alcohol/modification and synthesis/squaraine dye/hydrophilic grapheme

分类

化学化工

引用本文复制引用

孙琪,王丽秋,刘洋,郭晨晓,王鹏君,刘学龙,张晓博,郑立辉,刘丽萍..近红外聚乙烯醇荧光高分子材料的制备及性能[J].应用化学,2018,35(1):53-59,7.

基金项目

河北省自然科学基金资助课题(B2015203259) Supported by Hebei Natural Science Foundation(No.B2015203259) (B2015203259)

应用化学

OA北大核心CSCDCSTPCD

1000-0518

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