中国造纸学报2017,Vol.32Issue(4):27-31,5.
纤维素纳米纤维对聚乙烯醇复合膜性能的影响
Effect of Cellulose Nanofibers on the Property of Cellulose Nanofiber/Polyvinyl Alcohol Composite Film
摘要
Abstract
Cellulose nanofibers (CNF) prepared from 2,2,6,6-tetramethylpiperidiine-1-oxyl (TEMPO) oxidized bagasse pulp had large aspect ratio with diameters of 4 ~ 10 nm.Polyvinyl alcohol (PVA) was mixed with CNF to prepare CNF/PVA composite film,and the effects of glycerol and polyethylene glycol-400 (PEG-400) on light transmittance and mechanical properties of CNF/PVA film were studied.The application of pure CNF or PVA film was limited by their unsatisfied mechanical properties.The results showed that CNF/PVA film had both high mechanical strength and extensibility.The film containing 25% CNF had high light transmittance (> 90%) in 400 ~ 700 nm,high Young's modulus of 4.72 GPa and elongation at break of 6.92%.The light transmittances of the composite film declined with the addition of either glycerol or PEG-400.The glycerol and PEG-400 made the film more flexible but less stiff.关键词
纳米纤维素/复合膜/聚乙烯醇/高强度/拉伸性能Key words
cellulose nanofiber/composite film/polyvinyl alcohol/high strength/tensile property分类
化学化工引用本文复制引用
王志国,蒋杰,司玉丹,范一民..纤维素纳米纤维对聚乙烯醇复合膜性能的影响[J].中国造纸学报,2017,32(4):27-31,5.基金项目
国家林业公益性行业科研专项(201304609) (201304609)
中国博士后科学基金资助项目(164845). (164845)