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PEG包覆涂层对含碳纤维导电剂的锂硫正极材料的影响

谭杰成 田艳红 张学军 樊开乐

电化学2017,Vol.23Issue(6):654-660,7.
电化学2017,Vol.23Issue(6):654-660,7.DOI:10.13208/j.electrochem.160928

PEG包覆涂层对含碳纤维导电剂的锂硫正极材料的影响

Effect of PEG Coating on Properties of Lithium-Sulfur Battery Cathode Material Containing Carbon Fiber Conductive Agent

谭杰成 1田艳红 1张学军 1樊开乐1

作者信息

  • 1. 北京化工大学材料科学与工程学院,教育部碳纤维及功能高分子重点实验室,北京100029
  • 折叠

摘要

Abstract

The composite materials contained high modulus carbon fiber (HMCF) were successfully prepared by employing a ballmilling process based on the coating treatment of polyethylene glycol (PEG),and their structures and morphologies were characterized by scanning electron microscopy (SEM),X-ray powder diffraction (XRD),and X-ray photoelectron spectroscopy (XPS) techniques.The influences of PEG content on sulfur cathode capacity,cycle stability and rate performance were systematically studied.It was found that by the pre-coating of PEG,the cathode exhibited the high initial discharge specific capacity of 1312.5 mAh· g-1 at a current rate of 0.2C,and the reversible discharge capacity of 650 mAh· g1 was obtained after 50 cycles at a current rate of 200 mA· g-1,showing the remarkably improved cycling stability.

关键词

锂硫电池/硫正极/高模量碳纤维/包覆/聚乙二醇

Key words

lithium-sulfur battery/sulfur cathode/high modulus carbon fiber/coated/polyethylene glycol

分类

化学化工

引用本文复制引用

谭杰成,田艳红,张学军,樊开乐..PEG包覆涂层对含碳纤维导电剂的锂硫正极材料的影响[J].电化学,2017,23(6):654-660,7.

基金项目

北京市科委基金项目资助 ()

电化学

OA北大核心CSCDCSTPCD

1006-3471

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