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Na2O质量分数对高碱煤灰烧结强度影响

祁超 肖海平 王东旭 康志忠 孙保民

热力发电2018,Vol.47Issue(1):19-25,32,8.
热力发电2018,Vol.47Issue(1):19-25,32,8.DOI:10.19666/j.rlfd.201705029

Na2O质量分数对高碱煤灰烧结强度影响

Effect of sodium oxide content on ash sintering strength of high alkali coal

祁超 1肖海平 1王东旭 1康志忠 1孙保民1

作者信息

  • 1. 华北电力大学能源动力与机械工程学院,北京 102206
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摘要

Abstract

In order to study the effect of Na2O content on sintered strength of high alkali synthetic ash, the synthetic ash with different Na2O mass fractions was made into ash column and heated in a tubular furnace. The microcomputer control universal testing machine was applied to test the sintering strength of the synthetic ash, the X-ray diffraction (XRD) and scanning electron microscopy (SEM) were used to detect and observe the mineral composition and microstructure of synthetic ash. The results show that, with the increase of Na2O mass concentration, the sintered strength of the ash increased, the sodium compounds in the ash gradually changed from albite to nepheline, and the calcium compounds gradually transformed from anorthite to wollastonite and gehlenite. The low temperature eutectic system formed by minerals such as nepheline, wollastonite and gehlenite produced a large amount of liquid phase in the system, promoting the diffusion process of ash particles and increasing the sintering strength of the ash column. With the increase of Na2O mass concentration, the observed pore size between the ash particles decreased and the surface of the ash particles became more and more smooth.

关键词

Na2O/高碱煤/煤灰/烧结强度/矿物转化/XRD/SEM/低温共熔

Key words

Na2O/high alkali coal/coal ash/sintering strength/mineral conversion/XRD/SEM/low temperature melting

分类

化学化工

引用本文复制引用

祁超,肖海平,王东旭,康志忠,孙保民..Na2O质量分数对高碱煤灰烧结强度影响[J].热力发电,2018,47(1):19-25,32,8.

基金项目

国家科技支撑计划项目(2015BAA04B02) National Key Technology R&D Program (2015BAA04B02) (2015BAA04B02)

热力发电

OA北大核心CSTPCD

1002-3364

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