厦门大学学报(自然科学版)2018,Vol.57Issue(1):38-43,6.DOI:10.6043/j.issn.0438-0479.201703034
Kr离子辐照磷灰石陶瓷材料Ca10(PO4)6FxCl2-x(x=0,0.5,1.0,1.5和2.0)导致的非晶相变
Amorphization of Ca10(PO4)6FxCl2-x(x=0,0.5,1.0,1.5,2.0) Apatite Ceramics Caused by Kr Ion Irradiation
摘要
Abstract
A series of hexagonal polycrystalline apatite ceramics Ca10(PO4)6FxCl2-x(x=0,0.5,1.0,1.5,2.0)were synthesized by a conventional ceramic process,and the single-phase was confirmed by normal X-ray diffraction (XRD).Then,the apatite samples were irradiated with 800 keV Kr2+ at room temperature.The irradiated samples were characterized using grazing incidence X-ray dif-fraction (GIXRD).Crystalline-to-amorphous transition was observed in these apatite samples under 800 keV Kr2+ ion irradiation. However,it was found that the apatite sample with higher F proportion had smaller amorphous fraction with the same irradiation dose based on a series of irradiation experiments.Namely,the apatite with higher F proportion would have stronger ability to resist amorphization of Ca10 (PO4 )6 Fx Cl2-x .关键词
六方结构磷灰石/离子辐照/非晶转变Key words
hexagonal apatite/ion irradiation/amorphous transition分类
能源科技引用本文复制引用
董晓囡,张建,郭奇勋,焦绪丽,林绍辰,李宁..Kr离子辐照磷灰石陶瓷材料Ca10(PO4)6FxCl2-x(x=0,0.5,1.0,1.5和2.0)导致的非晶相变[J].厦门大学学报(自然科学版),2018,57(1):38-43,6.基金项目
国家自然科学基金(11205128,11227804) (11205128,11227804)