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PI/ZnO/Co3O4复合薄膜的制备及光催化性能研究

尹华平 贾苒 李青

印染助剂2018,Vol.35Issue(1):27-30,4.
印染助剂2018,Vol.35Issue(1):27-30,4.

PI/ZnO/Co3O4复合薄膜的制备及光催化性能研究

Preparation and photocatalytic properties of PI/ZnO/Co3O4 ternary films

尹华平 1贾苒 1李青1

作者信息

  • 1. 北京服装学院材料科学与工程学院,北京 100029
  • 折叠

摘要

Abstract

PI/ZnO/Co3O4 composite film with polyimide (PI) film as carrier was prepared by ion exchange method using cobalt nitrate, zinc nitrate as source of zinc and cobalt source. The composite films were characterized by X-ray diffraction (XRD), X ray fluorescence (XRF) and scanning electron microscope (SEM). Photocatalytic properties of composite thin films was studied using methylene blue as organic polutant. The results showed that ZnO of hexagonal wurtzite structure ion and Co3O4 of cubic structure were successfully loaded on the PI surface by ion exchange method, and the particle size reached the nanometer level. When the molar ratio of Co2+ and Zn2+ was 3:7, the time of ion exchange was 1.5 h, heating up to 460 ℃ and holding 2 h, the photocatalytic activity of the composite film was the best. When degradation time was 2 h, the degradation rate of methylene blue reached 98%.

关键词

聚酰亚胺/离子交换法/金属氧化物/光催化

Key words

polyimide/ion exchange method/metallic oxide/photocatalysis

分类

化学化工

引用本文复制引用

尹华平,贾苒,李青..PI/ZnO/Co3O4复合薄膜的制备及光催化性能研究[J].印染助剂,2018,35(1):27-30,4.

基金项目

国家自然科学基金项目(51273018) (51273018)

印染助剂

OA北大核心CSTPCD

1004-0439

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