中国塑料2018，Vol.32Issue(1)：44-50,7.DOI:10.19491/j.issn.1001-9278.2018.01.008
RDP与葫芦脲协同阻燃聚碳酸酯的研究
Study on Flame-retardant Synergy of Polycarbonate with RDP and Cucurbituril
摘要
Abstract
Flame-retardant polycarbonate (PC) compounds were prepared by combination of resiorcinol bis (diphenyl phosphate) (RDP) and cucurbituril (CB),and their flame-retardant performance was evaluated by limiting oxygen index,UL 94 vertical burning experiment and cone calorimetry.Moreover,their thermal behaviors were investigated by thermogravimetric analysis,and the morphology of their residual char was determined by SEM.The results indicated that the compounds obtained an optimum flame-retardant effect at the RDP/CB mass ratio of 6/2 and achieved an limited oxygen index of 32.5 vol ％,a UL 94 V-0 classification and a heat release rate of 266 kW/m2.The combination of RDP and CB improved the thermal stability of PC and enhance its char formation effectively.The morphological observation confirmed that a dense and compact intumescent char layer was formed due to a synergy between RDP and CB,consequently enhancing the flame retardancy upon PC.关键词
聚碳酸酯/芳基磷酸酯/葫芦脲/无卤阻燃/协同效应Key words
polycarbonate/aryl phosphate/cucurbituril/halogen-free flame retardant/synergistic effect分类
化学化工引用本文复制引用
许博,朱向东,姚可欣,张琛,钱立军,谭曾凯..RDP与葫芦脲协同阻燃聚碳酸酯的研究[J].中国塑料,2018,32(1):44-50,7.基金项目
国家自然科学基金资助项目(51103002) （51103002）
北京工商大学大学生科学研究与创业行动计划(201710011180) （201710011180）
北京工商大学两科基金培育项目(LKJJ2017-17) （LKJJ2017-17）
