化工进展2018,Vol.37Issue(2):628-636,9.DOI:10.16085/j.issn.1000-6613.2017-0926
有机金属骨架材料在电化学储能领域中的研究进展
Research progress of MOFs-based materials in electrochemical energy storage
摘要
Abstract
Metal organic frameworks(MOFs)have attracted great attention because of their high specific surface area,adjustable pore structure and diverse composition,and the applications of MOFs have great prospects in various fields,especially for electrochemical energy storage in which great progress has made.This article summarizes the application of MOFs based materials in the field of electrochemical energy storage for lithium-sulfur batteries,lithium-ion batteries and supercapacitors in recent years.The mechanism of MOFs and their composites as host of lithium-sulfur battery cathode was introduced in detail.The physical encapsulation and chemical coordination of MOFs on active substances were discussed.In addition,it described the improved battery performance when the MOFs derived carbon material with unique pore structure,strong conductivity and rich active sites was used as the electrode material.Finally,the MOFs based materials in electrochemical energy storage is prospected and the control of heteroatoms and the design of the channels in the MOFs-based materials are thought as the focus of future research.关键词
金属有机骨架/配合物/复合材料/电化学/电极材料Key words
metal organic frameworks/complexes/composite/electrochemistry/electrode material分类
数理科学引用本文复制引用
陈丹,杨蓉,张卫华,李润秋,朱序阳,路蕾蕾..有机金属骨架材料在电化学储能领域中的研究进展[J].化工进展,2018,37(2):628-636,9.基金项目
国家自然科学基金(21503166),国家国际科技合作专项项目(2015DFR50350),陕西省科技计划(2017GY-160)及西安理工大学校创新项目(2015CX011). (21503166)