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ZnO负载SnO2复合材料的制备及其气敏性能

魏莹 仪桂云 王晓冬 许亚威 周利星

化工进展2018,Vol.37Issue(2):651-657,7.
化工进展2018,Vol.37Issue(2):651-657,7.DOI:10.16085/j.issn.1000-6613.2017-0907

ZnO负载SnO2复合材料的制备及其气敏性能

Preparation and sensing properties of ZnO supporting SnO2 nanocomposites

魏莹 1仪桂云 2王晓冬 1许亚威 2周利星1

作者信息

  • 1. 河南理工大学材料科学与工程学院,河南 焦作454000
  • 2. 河南理工大学环境友好型无机材料河南省高校重点实验室培育基地,河南 焦作454000
  • 折叠

摘要

Abstract

SnO2/ZnO composites were synthesized by a facile hydrothermal method using SnCl4·5H2O and Zn(AC)2·2H2O as the raw material and NaOH as the precipitant,which makes SnO2nanoparticles adhere to the surface of silkworm chrysalis-like ZnO.The structure and morphology of the obtained materials were characterized by XRD,TEM,HRTEM and BET.And the effects of temperature,ethanol concentration and other factors on the sensitivity were inverstigated.The results confirmed that the composite materials were SnO2nanoparticles and silkworm chrysalis-like ZnO.The SnO2nanoparticles were distributed on the surface of ZnO.The SnO2/ZnO composite exhibited good gas-sensing properties,and the sensitivity of the sensor to 200μL/L ethanol was 39.68 at the optimum operating temperature (240℃),which were almost double of that of the individual SnO2(24.53)and ZnO sensor(17.8).

关键词

二氧化锡/氧化锌/粒子/水热/复合材料/气敏性能/选择性

Key words

SnO2/ZnO/particles/hydrothermal/composites/gas-sensing properties/selectivity

分类

化学化工

引用本文复制引用

魏莹,仪桂云,王晓冬,许亚威,周利星..ZnO负载SnO2复合材料的制备及其气敏性能[J].化工进展,2018,37(2):651-657,7.

基金项目

国家自然科学基金(51404097,61474038,51404097)、河南省科技攻关项目(132102210251)及河南省高等学校重点科研项目计划(15A430027). (51404097,61474038,51404097)

化工进展

OA北大核心CSCDCSTPCD

1000-6613

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