生物质化学工程2018，Vol.52Issue(1)：41-52,12.DOI:10.3969/j.issn.1673-5854.2018.01.007
木质素模型化合物合成研究的现状与展望
Status and Prospect of Lignin Model Compounds Synthesis
摘要
Abstract
The research status of lignin model compounds synthesis was comprehensively summarized. Three main pathways of lignin monomer synthesis were introduced, including shikimic acid pathway, phenylpropane metabolizing pathway, and ester reduction pathway. The two theories of lignin monomer polymerization were sketched, i.e., the random polymerization theory(or free radical combinatorial coupling theory) which was widely accepted by academia and the controversial strict regulation polymerization theory. The research development of the chemical synthesis methods and mechanism of dimer,trimer and polymer from lignin model compounds bounded by β-O-4,α-O-4,5-5′, and β-5′ bonds was illustrated. Meanwhile, some problems and countermeasures during the lignin chemical synthesis process were pointed out and the development direction of lignin model compounds synthesis research was confirmed.关键词
木质素/模型物/单体/二聚体/化学合成Key words
lignin/model compounds/monomer/dimer/chemical synthesis分类
化学化工引用本文复制引用
赵新坤,李赫龙,佘雕,孙润仓..木质素模型化合物合成研究的现状与展望[J].生物质化学工程,2018,52(1):41-52,12.基金项目
国家自然科学基金资助项目(31772390,31370368) （31772390,31370368）
中科院西部之光人才专项(K318021401) （K318021401）
