高校化学工程学报2018，Vol.32Issue(1)：92-100,9.DOI:10.3969/j.issn.1003-9015.2018.01.013
反胶团萃取盐酸溶液中钛的动力学
Kinetics of Titanium Extraction from Hydrochloric Acid Solution with Reverse Micelles
摘要
Abstract
In order to improve titanium (IV) extraction efficiency from hydrochloric acid solution, kinetics of titanium (IV) extraction from hydrochloric acid solution with tributylphosphate (TBP) and decanol in kerosene was investigated (using a Lewis cell based on reverse micelle extraction). Effects of stirring speed, temperature, interfacial area and reactant concentration were discussed. The results show that the extraction speed increases with the increase of stirring speed, interfacial area, temperature, extractant concentration, titanium (IV) concentration and chloride ion concentration. The activation energy of extraction is 31.73 kJ?mol-1, and the process is controlled by both diffusion in aqueous phase and reaction. The kinetic equation of titanium (IV) extraction from hydrochloric acid solution with TBP and decanol is obtained.关键词
动力学/反胶团萃取/钛/盐酸Key words
kinetics/reversed micelle extraction/titanium/hydrochloric acid分类
化学化工引用本文复制引用
毛雪华,刘代俊..反胶团萃取盐酸溶液中钛的动力学[J].高校化学工程学报,2018,32(1):92-100,9.基金项目
国家自然科学基金(21076131). （21076131）
