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臭氧催化氧化处理废水的催化剂适配

贺晓凌 孙琪 李媛媛 邹凯健 韩馨

天津工业大学学报2018,Vol.37Issue(1):32-37,42,7.
天津工业大学学报2018,Vol.37Issue(1):32-37,42,7.DOI:10.3969/j.issn.1671-024x.2018.01.006

臭氧催化氧化处理废水的催化剂适配

Catalyst adaptation of ozone catalytic oxidation for wastewater treatment

贺晓凌 1孙琪 2李媛媛 1邹凯健 2韩馨1

作者信息

  • 1. 天津工业大学环境与化学工程学院,天津300387
  • 2. 天津工业大学天津市水质安全评价与保障技术工程中心,天津300387
  • 折叠

摘要

Abstract

In order to investigate the removal efficiency of organic pollutants in industrial wastewater by different ozone catalytic oxidation systems, the different supported catalyst systems were prepared by the dipping-calcination method using molecular sieve as carrier and acetate solution of Mn, Cu and Ni as the precursor. Through the adaptation of different catalysts,the catalyst system was optimized and screened to obtain the heterogeneous o-zone catalytic oxidation system suitable for industrial wastewater treatment.The results showed that the loading rate of three component catalytic system was optimal,up to 6.5%.The catalyst/O3system can significantly im-prove the COD removal rate of wastewater.The removal rate of COD in the three component catalytic system was highest among three catalytic systems and that was up to 59% when the molar ratio of Mn,Cu and Ni was 1:1:3.The pH value of wastewater was dramatically decreased by treatment of catalyst/O3system,which also proved that the combination of catalyst and ozone had a significant degradation effect on the organic compounds in wastewater.

关键词

工业废水/臭氧/催化剂/臭氧催化氧化

Key words

industrial wastewater/ozone/catalyst/catalytic ozonation

分类

化学化工

引用本文复制引用

贺晓凌,孙琪,李媛媛,邹凯健,韩馨..臭氧催化氧化处理废水的催化剂适配[J].天津工业大学学报,2018,37(1):32-37,42,7.

基金项目

天津市自然科学基金资助项目(16JCYBJC23800) (16JCYBJC23800)

天津市大学生创新创业训练计划资助项目(201710058089) (201710058089)

天津工业大学学报

OA北大核心CSTPCD

1671-024X

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