电源技术2017，Vol.41Issue(11)：1614-1616,1651,4.
CoS2材料的纯化工艺优化及其在热电池中的应用
Optimization of purification technology and its application of CoS2 in thermal battery
摘要
Abstract
Heat treatment of CoS2 was conducted in a vacuum tube furnace in order to get rid of impurity of sulfur.The morphology,crystal structure and thermal stability of CoS2 was characterized by SEM,XRD and TG-DSC,respectively.The effect of process parameters on material properties was also studied.The test results show that morphologies of CoS2 are changed slightly at the treated temperature of 500-560 ℃,and the aggregate about micro level appears between particles;the crystal structure of CoS2is changed to Co3S4 at the treated temperature of 550 ℃ for 18 h,which is maintained as pyrite CoS2 treated for 10 h;DSC curves of CoS2treated at 550 ℃ shows smooth level without impurity peak.The automatic discharge system of single thermal battery was used for the electrical performance test.The pulse discharge curve shows that purified CoS2 displays higher discharge voltage,larger capacity and better anti pulse performance.关键词
热电池/CoS2/纯化/热稳定性/电化学性能Key words
thermal battery/CoS2/purification/thermal stability/electrochemical property分类
信息技术与安全科学引用本文复制引用
杨潇薇,李立,兰伟,刘效疆..CoS2材料的纯化工艺优化及其在热电池中的应用[J].电源技术,2017,41(11):1614-1616,1651,4.基金项目
中国工程物理研究院科学技术发展基金(2014B0302043) （2014B0302043）
