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MnO2/石墨烯水热合成及其在热电池中的应用

杨潇薇 杨坤坤 杨兆堂 兰伟 杨少华

电源技术2018,Vol.42Issue(1):61-64,4.
电源技术2018,Vol.42Issue(1):61-64,4.

MnO2/石墨烯水热合成及其在热电池中的应用

Hydrothermal synthesis of MnO2/graphene and its application in thermal battery

杨潇薇 1杨坤坤 2杨兆堂 1兰伟 1杨少华2

作者信息

  • 1. 中国工程物理研究院电子工程研究所,四川绵阳621999
  • 2. 沈阳理工大学环境与化学工程学院,辽宁沈阳110159
  • 折叠

摘要

Abstract

MnO2/grapheme (MnO2/G) composites were synthesized by hydrothermal method.The effect of reactant concentration on the morphology,structure and composition of MnO2/G was studied by SEM,XRD and FT-IR.MnO2/G was used as the cathode material to prepare the thermal cell,and the pulse discharge curve was tested.The test results show that with the decrease of manganese source concentration in the reaction system,the phase structure is changed from δ-MnO2 into α-MnO2,and the morphology of product is changed from ball type structure into nanorod structure.When the single cell is discharged at current density of 10 mA/cm2,during which 200 mA/cm2 pulse current is applied,the initial discharge voltage is 3.192 V and there is a high and stable discharge platform during the discharge.The initial internal resistance of single cell is 3.63 Ω,and with increase of discharge depth,the internal resistance of the battery firstly decreases and then increases.

关键词

热电池/MnO2/石墨烯/水热法/电性能

Key words

thermal battery/MnO2/grapheme/hydrothermal synthesis/electric performance

分类

信息技术与安全科学

引用本文复制引用

杨潇薇,杨坤坤,杨兆堂,兰伟,杨少华..MnO2/石墨烯水热合成及其在热电池中的应用[J].电源技术,2018,42(1):61-64,4.

基金项目

中国工程物理研究院科学技术发展基金(2014B0302043) (2014B0302043)

电源技术

OA北大核心CSTPCD

1002-087X

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