分析测试学报2017，Vol.36Issue(11)：1397-1400,4.DOI:10.3969/j.issn.1004-4957.2017.11.018
珊瑚中五环半缩醛甾体的结构解析
Structural Analysis of a Pentacyclic Hemiacetal Steroid Isolated from Coral Sinularia sp.
摘要
Abstract
A pentacyclic hemiacetal steroid was isolated and purified by chromatography with silica gel,Sephadex LH-20 column as well as HPLC.Its plane structure was identified by nuclear magnetic resonance spectroscopy (NMR spectra)and mass spectrometry.By determining and comparing the calculated values of CD,it is determined that the structure of the compound is(8R,9S,10R,13R,14S,17R,18R,20S,22R)-cholesta-1,4-dien-18-al,22-hydroxy-3-oxo-,cyclic 18,22-(acetyl acetal).The compound was isolated from Sinularia sp.for the first time.关键词
珊瑚/五环半缩醛甾醇/结构解析Key words
coral/pentacyclic hemiacetal steroid/structure elucidation分类
化学化工引用本文复制引用
吴嘉诚,林嘉莉,廖赣莉,廖小健,徐石海..珊瑚中五环半缩醛甾体的结构解析[J].分析测试学报,2017,36(11):1397-1400,4.基金项目
国家自然科学基金(41376155,21672084) （41376155,21672084）
广东省自然科学基金(2016A030310095) （2016A030310095）
广州市科技项目(201704030042) （201704030042）
暨南大学科研培育与创新基金研究项目(21616113) （21616113）
