分析化学2018，Vol.46Issue(3)：422-431,10.DOI:10.11895/j.issn.0253-3820.171436
基于电化学方法研究猪粪堆肥过程溶解性有机物电子转移能力演变规律
Electron Transfer Capacities of Dissolved Organic Matter Derived from Swine Manure Based on Eletrochemical Method
摘要
Abstract
Dissolved organic matter (DOM) is the most active fraction of compost organic matter. The presence of the redox-active functional groups in DOM allows it to act an electron shuttle to promote the electron transfer between microorganisms and terminal electron acceptors. In this study, the electron transfer capacities (ETCs) of compost DOM samples at eight different composting stages were determined by electrochemical method. The 2, 2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS) and Diquat dibro-mide monohydrate (DQ) were used to measured electron donating capacity (EDC) and electron accepting capacity(EAC) with working voltage 0.61 V/-0.49 V,respective. The evolution characteristics of the chemical structures and components were analyzed by combining the three-dimensional fluorescence spectra,fourier transform infrared (FTIR) spectra and elemental analysis. The results showed that the electron donating capacity(EDC) of DOMincreased from 16.850 μmol e-/(g C) to 22.077 μmol e-/(g C), The corresponding electron accepting capacity (EAC) decreased from 1.866 μmol e-/(g C)to 1.779 μmol e-/(g C). The results of three-dimensional fluorescence spectroscopy show that the relative contents of humuc-likeand protein-like components gradually increased and decreased, respectively, during the composting process. The humuc-like components were the main contributor for the ETC of DOM. FTIR spectra shows that there was no significant change in the hydroxyl and carboxyl group contentsof DOM during composting, suggesting no contribution of these function groups to the ETC of DOM. The elemental analysis showed that the content of oxygen in the DOM increased during the composting process, while the sulfur-containing group may be dominated contributor forits ETC.关键词
堆肥/水溶性有机物/电子转移能力/三维荧光/红外光谱Key words
Composting/Dissolved organic matter/Electron transfer capacity/Three-dimensional fluorescence/Infrared spectroscopy引用本文复制引用
唐朱睿,黄彩红,檀文炳,何小松,张慧,李丹,席北斗..基于电化学方法研究猪粪堆肥过程溶解性有机物电子转移能力演变规律[J].分析化学,2018,46(3):422-431,10.基金项目
本文系国家自然科学基金项目(No.51508540)资助 This work was supported by the National Natural Science Foundation of China(No.51508540). （No.51508540）
