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基于响应曲面法的磷酸分解磷矿研究

李茂刚 罗康碧 李沪萍 苏毅 梅毅

硅酸盐通报2018,Vol.37Issue(1):41-46,6.
硅酸盐通报2018,Vol.37Issue(1):41-46,6.

基于响应曲面法的磷酸分解磷矿研究

Phosphate Rock Decomposition by Phosphoric Acid Based on Response Surface Method

李茂刚 1罗康碧 2李沪萍 3苏毅 3梅毅3

作者信息

  • 1. 昆明理工大学化学工程学院,昆明 650500
  • 2. 昆明理工大学云南省高校磷化工重点实验室,昆明 650500
  • 折叠

摘要

Abstract

Based on phosphorite resources which largely exist in Yunnan Province, effects of phosphoric acid concentration, liquid-solid ratio and temperature on the conversion rate of phosphorite were investigated.A regression model of phosphoric acid decomposing phosphorite process were established through experimental design of response surface method(RSM).The relationship among the conversion of phosphate rock and the phosphoric acid concentration,liquid-solid ratio and temperature were reflected by this regression model.The optimal technological conditions of decomposition were temperature of 110℃,liquid-solid ratio of 9 and phosphoric acid concentration of 42% P2O5through this model.And the conversion rate of phosphate rock reached 99.29% under this process condition.Compared with the predicted value, the relative error was less than 1%.It indicated that the relationship between the parameters could accurately reflected by the regression model.Thua, the prediction and optimizaiton about decomposition of phosphate rock could be used this model.

关键词

磷矿/磷酸/分解/响应曲面

Key words

phosphorite/phosphoric acid/decomposition/response surface

分类

化学化工

引用本文复制引用

李茂刚,罗康碧,李沪萍,苏毅,梅毅..基于响应曲面法的磷酸分解磷矿研究[J].硅酸盐通报,2018,37(1):41-46,6.

基金项目

国家自然科学基金(21666015) (21666015)

云南省人才培养项目(kksy201305126) (kksy201305126)

硅酸盐通报

OA北大核心CSTPCD

1001-1625

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