硅酸盐通报2018，Vol.37Issue(1)：309-314,320,7.
不同晶粒大小Silicalite-1分子筛的合成及其MTP反应性能
Synthesis of Silicalite-1 Zeolite with Different Particle Size and Its Application in MTP Reaction
摘要
Abstract
A series of Silicalite-1 zeolites were synthesized with different templates and pH regulators.The obtained samples were characterized by XRD, N2adsorption-desorption, SEM, NH3-TPD and FT-IR. The results indicate that TPA+exhibited the best structure-directing performance due to its stable tetrahedral structure; colloidal alkalinity is verified through changing pH regulators, as a result the alkalinity decreased and the grain size increased.The as-synthesized Silicalite-1 catalyst obtained from optimum conditions is applied to MTP reaction,compared with industrialized lurgi catalyst,the Silicalite-1 catalyst has the characteristics of the higher selectivity to propene and the lower deactivation rate.关键词
Silicalite-1/模板剂/碱源/MTPKey words
Silicalite-1/template/pH regulator/MTP分类
能源科技引用本文复制引用
张洪菡,张善鹤,孟哲,李春义,山红红..不同晶粒大小Silicalite-1分子筛的合成及其MTP反应性能[J].硅酸盐通报,2018,37(1):309-314,320,7.基金项目
国家重点基础研究发展计划(973计划)(2012CB215006) （973计划）
