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降冰片烯类化合物的合成与表征

孙敏青 马欣 屈凤波 杨振强 陈辉 张银龙

合成材料老化与应用2018,Vol.47Issue(1):48-50,3.
合成材料老化与应用2018,Vol.47Issue(1):48-50,3.

降冰片烯类化合物的合成与表征

The Synthesis and Characterization of the Norbornene and Its Derivates

孙敏青 1马欣 1屈凤波 2杨振强 1陈辉 1张银龙1

作者信息

  • 1. 河南省科学院化学研究所有限公司,河南郑州450002
  • 2. 河南金上化成化工科技有限公司,河南郑州450002
  • 折叠

摘要

Abstract

In this paper,acrylic compounds and C5 were adopted as raw materials,and tert-butyl catechol and [Cu2(dppm)2(C7H7N)(μ-NO3)](NO3) were selected as catalysts to synthesis norbornene and its derivates. Ex-perimental research have shown that the target products were obtained through the Diels-Alder reaction between cy-clopentadiene in C5 and acrylic compounds with 74.1% ~87.8% yield at the temperature of -15℃ ~5℃.

关键词

混合碳五/叔丁基邻苯二酚/降冰片烯

Key words

C5/tert-butyl catechol/norbornene

分类

化学化工

引用本文复制引用

孙敏青,马欣,屈凤波,杨振强,陈辉,张银龙..降冰片烯类化合物的合成与表征[J].合成材料老化与应用,2018,47(1):48-50,3.

基金项目

河南省科技创新杰出青年基金(174100510018) (174100510018)

河南省科技开放项目(17210600063) (17210600063)

合成材料老化与应用

OACSTPCD

1671-5381

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