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热老化对RDX基含铝压装炸药装药发射安全性的影响

张林军 杜姣姣 栾洁玉 贾林 刘文亮 常海 王芳芳

含能材料2018,Vol.26Issue(2):156-160,5.
含能材料2018,Vol.26Issue(2):156-160,5.DOI:10.11943/j.issn.1006-9941.2018.02.008

热老化对RDX基含铝压装炸药装药发射安全性的影响

Effect of Thermal-aging on Launching Safety of RDX-based Aluminized and Pressed Explosive Charge

张林军 1杜姣姣 1栾洁玉 1贾林 1刘文亮 1常海 1王芳芳1

作者信息

  • 1. 西安近代化学研究所,陕西西安710065
  • 折叠

摘要

Abstract

To investigate the effect of thermal aging on the overloading safety of explosive charge,the accelerating aging of RDX-based aluminized and pressed explosive charge was performed at high temperature of 71 ℃ for 39 days.The launching safety of charge before and after aging were checked by drop hammer loading device and the effect of explosive grain structure,deterrent and binder content and quality of RDX crystal on the launching safety of charge was analyzed.Results show that under the same drop hammer loading condition,the probability of occurring combustion and explosion of unaged sample is larger than aged sample,after aging,the structure of explosive grain of aged sample is completer,the binder of explosive grain is softened and migrated,micro pore is reduced and closed,the content of deterrent and binder of explosive grain surface increases from 5.90% to 6.20%.Compared with the RDX crystal particles before aging,the half width of Raman charavteristic peak of the RDX crystal particles after aging decreases,especially full width at half maxima for charavteristic peak at 345 cm-1 decreases by 42.2%.Showing that in the aging process,the softening and migration of deterrent and binder in explosive grain,micro defect repair,surface passivation and improvement of quality of RDX crystal etc.factors are the main reasons of lanching safety of aged charge is better than that of unaged charge.

关键词

RDX基含铝压装炸药装药/热老化/发射安全性/性能变化

Key words

RDX-based aluminized and pressed explosive charge/thermal aging/launching safety/performance change

分类

军事科技

引用本文复制引用

张林军,杜姣姣,栾洁玉,贾林,刘文亮,常海,王芳芳..热老化对RDX基含铝压装炸药装药发射安全性的影响[J].含能材料,2018,26(2):156-160,5.

基金项目

国防重大基础科研项目(00402040502) (00402040502)

含能材料

OA北大核心CSCDCSTPCD

1006-9941

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