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钢渣对磷酸盐水泥基材料性能的影响机制

吴凯 叶钰燕 施惠生 居正慧

同济大学学报(自然科学版)2018,Vol.46Issue(1):87-93,7.
同济大学学报(自然科学版)2018,Vol.46Issue(1):87-93,7.DOI:10.11908/j.issn.0253-374x.2018.01.013

钢渣对磷酸盐水泥基材料性能的影响机制

Effect and Mechanism of Steel Slag on Performance of Magnesium Phosphate Cements

吴凯 1叶钰燕 2施惠生 2居正慧1

作者信息

  • 1. 同济大学材料科学与工程学院,上海201804
  • 2. 同济大学先进土木工程材料教育部重点实验室,上海201804
  • 折叠

摘要

Abstract

This work investigated the feasibility of reusing steel slag as raw materials in preparing magnesium phosphate cement (MPC).The effect of steel slag on the setting time,hydration process,mechanical properties and microstructure of prepared cements was determined.The results show that the influence of steel slag on the performance of magnesium phosphate cement exhibits a similar trend as that of fly ash.The addition of 10% steel slag would accelerate the hardening of prepared cement due to the presence of CaO and the formed calcium hydroxide.The hardness of steel slag would also increase the compressive strength.With increasing the steel slag substitutional level,the content of hydration products would decreases,while the porosity increases and micorstructure become loose as a result.The hydration of fCaO would do a detrimental effect on the mechanical properties of MPC.The hydration products detected in X-ray diffraction(XRD) patterns of steel slag blended MPC is the same as those of reference.However,there is more microcrack present in the hardened paste containing 40% of steel slag.

关键词

磷酸盐水泥/钢渣/粉煤灰/性能/机制

Key words

magnesium phosphate cement/steel slag/fly ash/performance/mechanism

分类

建筑与水利

引用本文复制引用

吴凯,叶钰燕,施惠生,居正慧..钢渣对磷酸盐水泥基材料性能的影响机制[J].同济大学学报(自然科学版),2018,46(1):87-93,7.

基金项目

“十三五”国家重点研发计划(2016YFC0700802),国家自然科学基金(51608382,51378390,51402216),污染控制与资源化研究国家重点实验室开放课题 (2016YFC0700802)

同济大学学报(自然科学版)

OA北大核心CSCDCSTPCD

0253-374X

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