材料科学与工程学报2017，Vol.35Issue(6)：921-926,6.DOI:10.14136/j.cnki.issn 1673-2812.2017.06.013
环氧基多支链反应型乳化剂的制备及其性能
Preparation and Properties of Epoxy-based High-branched Polymerizable Emulsifier
沈如宝 1于松禾 1王传鑫 1钱军1
作者信息
- 1. 华东理工大学材料科学与工程学院,上海200237
- 折叠
摘要
Abstract
Epoxy-based high-branched polymerizable emulsifiers have been synthesized by the reaction of Toluene 2,4-diisocynate(TDI),dimethylolbutanoic acid(DMBA),polyethylene glycol(PEG),and bisphenol A epoxy resin.The epoxide values of the synthesized emulsifiers were about 0.1mol/100g,and thus they can be used as emulsifiers for e-44 and self-emulsified epoxy resin.The reaction procedures were monitored through chemical titration (hydrochloride acid-acetone method) and FT-IR.Polyethylene glycol with various molecular weights was used to investigate the influence of molecular weights on emulsifiers.The studies reveal that with the increase of the PEG's molecular weight,the emulsifier's cloud point,HLB value,and critical micellar concentration increase and Γ decreases.Furthermore,S-3 is the optimal emulsifier.When emulsion contains 20/100 of epoxy resin/S-3,its properties of viscosity,particle size,stability,and epoxide value are relatively optimal.关键词
反应型乳化剂/环氧树脂乳液/物理性能Key words
polymerizable emulsifier/epoxy resin emulsion/physical properties分类
化学化工引用本文复制引用
沈如宝,于松禾,王传鑫,钱军..环氧基多支链反应型乳化剂的制备及其性能[J].材料科学与工程学报,2017,35(6):921-926,6.
