地质科技情报2018，Vol.37Issue(1)：108-114,7.DOI:10.19509/j.cnki.dzkq.2018.0114
渤中地区不同热解实验条件下的烃源岩生烃动力学研究
Hydrocarbon Generation Kinetics of Source Rocks under Different Pyrolysis Conditions in Bozhong Area
摘要
Abstract
To study oil and gas generation activation energy of different samples under different pyrolysis experiments,open system anhydrous pyrolysis and confined system hydrous pyrolysis are performed on lacustrine shale source rock,raw rock and kerogen samples from Bozhong area.Source rock samples are from different sags and different intervals,and have different organic matter abundance,kerogen type and maturity.The results shows that kerogen type and maturity have important influence on oil generation activation energy,and mean oil generation activation energy increases as organic matter type becomes poorer and maturity is higher.Different sags,source rock intervals and sample type have no obvious influence on mean oil generation activation energy,but sample type influences the distribution.Hydrocarbon generation activation energy distribution of raw rocks is more concentrated than kerogen.Gas generation activation energy of mature source rocks is 11-17 kJ/mol higher than that of low mature source rocks.Compared with open system anhydrous pyrolysis,confined system hydrous pyrolysis has more concentrated activation energy distribution including primary and secondary cracking.Confined system hydrous pyrolysis of low mature source rock raw samples and mature source rock kerogen samples for oil and gas generation kinetics respectively are recommended.关键词
烃源岩/生烃模拟实验/生烃动力学/渤中Key words
source rock/hydrocarbon generation simulation experiment/hydrocarbon generation kinetics/Bozhong分类
天文与地球科学引用本文复制引用
王军,王清斌,王飞龙,黄振,陈容涛..渤中地区不同热解实验条件下的烃源岩生烃动力学研究[J].地质科技情报,2018,37(1):108-114,7.基金项目
国家科技重大专项“渤海辽东湾地区潜在富烃凹陷成藏研究与有利勘探方向预测”(2016ZX05024-002-006) （2016ZX05024-002-006）
