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废铝基/钯催化剂碱性浸出废液制备拟薄水铝石的研究

杜安睿 姜涛 李骞 徐斌 杨永斌

矿产保护与利用Issue(1):112-116,122,6.
矿产保护与利用Issue(1):112-116,122,6.DOI:10.13779/j.cnki.issn1001-0076.2018.01.020

废铝基/钯催化剂碱性浸出废液制备拟薄水铝石的研究

Study on the Preparation of Pseudoboehmite Using the Alkaline Leachate of Aluminum Base/Palladium Catalysts

杜安睿 1姜涛 1李骞 1徐斌 1杨永斌1

作者信息

  • 1. 中南大学 资源加工与生物工程学院,湖南 长沙410083
  • 折叠

摘要

Abstract

The properties and microstructure of pseudoboehmite prepared by the alkaline leachate of aluminum base/palladium catalysts using sodium aluminate-CO2neutralization method at different conditions were studied. The results indicated that the granular appearance of pseudoboehmite was determined by the terminal reaction pH and aging temperature,while the particle size was charac-terized by the final pH,aging temperature and aging time. Under the conditions of pH=10.5,ag-ing temperature of 90 ℃ and aging time of 4 h,the pure pseudoboehmite product with specific sur-face area of 282 m2/g and dispersion index of 96.2% can be obtained.

关键词

拟薄水铝石/微观结构/碳化法/废铝基催化剂/钯催化剂/碱性废液

Key words

pseudoboehmite/microstructure/carbonization method/spent Al2O3-based catalyst/palladium catalyst/alkaline leachate

分类

矿业与冶金

引用本文复制引用

杜安睿,姜涛,李骞,徐斌,杨永斌..废铝基/钯催化剂碱性浸出废液制备拟薄水铝石的研究[J].矿产保护与利用,2018,(1):112-116,122,6.

基金项目

国家自然科学基金(51574284),云南省校科技合作项目(2013IB020) (51574284)

矿产保护与利用

OACSTPCD

1001-0076

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