林产化学与工业2018，Vol.38Issue(1)：59-65,7.DOI:10.3969/j.issn.0253-2417.2018.01.009
SI-ATRP法制备纳米纤维素增强热塑性弹性体及其性能研究
Synthesis and Characterization of Self-reinforced Cellulose Nanocrystals Based Thermoplastic Elastomers by SI-ATRP
摘要
Abstract
Degreasing cotton was used to prepare an initiator for surface-initiated atom transfer radical polymerization(SI-ATRP). Subsequently,SI-ATRP of tetrahydrofurfuryl methacrylate (THFMA) and lauryl methacrylate (LMA) was carried out in the presence of sacrificial initiator (EBiBr) to prepared self-reinforced CNCs based thermoplastic elastomers (CTPEs). FT-IR, 1H NMR and GPC were applied to characterize the structure of CTPEs. DSC analysis showed that the glass transition temperature (Tg) of CTPEs was increased from -0.04℃ to 22.58℃ with the increasing of THFMA content. Mechanical properties test showed that the tensile strength was increased from 0.14 MPa to 6.17 MPa with the increasing of THFMA content in the feeding. And compared to the linear copolymer P(LMA-co-THFMA) which has the same THFMA/LMA composition,the tensile strength of CTPEs was increased by 3 times,which indicated that CNCs could greatly improve the mechanical properties of CTPEs.关键词
表面引发原子转移自由基聚合法/纳米纤维素/热塑性弹性体Key words
SI-ATRP/cellulose nanocrystals (CNCs)/thermoplastic elastomer分类
化学化工引用本文复制引用
卢传巍,郭腾飞,王春鹏,储富祥,王基夫..SI-ATRP法制备纳米纤维素增强热塑性弹性体及其性能研究[J].林产化学与工业,2018,38(1):59-65,7.基金项目
中国林科院中央级公益性科研院所基本科研业务费专项资金资助(CAFYBB2016ZD007) （CAFYBB2016ZD007）
