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星状VO2纳米结构的制备及电化学性能研究

袁江涛 李坤振 刘中飞 熊狂伟 金绍维 王佩红

人工晶体学报2018,Vol.47Issue(1):71-76,6.
人工晶体学报2018,Vol.47Issue(1):71-76,6.

星状VO2纳米结构的制备及电化学性能研究

Fabrication and Electrochemical Properties of the Star-like VO2Nanostructure Materials

袁江涛 1李坤振 1刘中飞 1熊狂伟 1金绍维 1王佩红2

作者信息

  • 1. 安徽大学物理与材料科学学院,合肥230601
  • 2. 安徽省信息材料与器件重点实验室,合肥230601
  • 折叠

摘要

Abstract

The star-like VO2nanostructures were successfully fabricated via hydrothermal method as high-performance electrode material, using V2O5and oxalic acid as raw materials.The phase compositions, element and electronic valence state, and morphologies of the samples were characterized by X-ray diffraction spectrometry(XRD), X-ray photoelectron spectra(XPS)and scanning electron microscopy (SEM),respectively.The electrochemistry measurements show that the star-like VO2having a specific capacitance of 574.75 F· g-1at a current density of 0.2 A· g -1,and achieves a high energy density of 51.09 Wh· kg -1.The star-like VO2has good cycling stability with capacitance retention of 90.2%after 4250 charge-discharge cycles,which exhibits an excellent capacitance performance.

关键词

星状二氧化钒/电极材料/比电容/能量密度

Key words

star-like VO2/electode material/specific capacitance/energy density

分类

化学化工

引用本文复制引用

袁江涛,李坤振,刘中飞,熊狂伟,金绍维,王佩红..星状VO2纳米结构的制备及电化学性能研究[J].人工晶体学报,2018,47(1):71-76,6.

基金项目

国家自然科学基金(61671017) (61671017)

人工晶体学报

OA北大核心CSTPCD

1000-985X

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