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浮选过程中金属离子对异极矿硫化的影响

张国范 张凤云

中南大学学报(自然科学版)2017,Vol.48Issue(7):1689-1696,8.
中南大学学报(自然科学版)2017,Vol.48Issue(7):1689-1696,8.DOI:10.11817/j.issn.1672-7207.2017.07.001

浮选过程中金属离子对异极矿硫化的影响

Effect of metal ions on sulfiding flotation of hemimorphite

张国范 1张凤云1

作者信息

  • 1. 中南大学资源加工与生物工程学院,湖南长沙,410083
  • 折叠

摘要

Abstract

The influences of sulfidization and metal ions on flotation of hemimorphite were studied through flotation tests,solution chemistry calculations,zeta potential measurement and XPS test.The results show that it is hard to collect hemimorphite well by using xanthate at normal temperature.Though Na2S can not improve the collection of hemimorphite,it can obviously make collection better by reconditioning with metal ions after sulfidization.The strength of the activation sequence from small to big is:Cu2+,Zn2+ or Pb2+.HS-is the main composition.The activation ability and pH value of metal ions are related with the concentration of positively charged components of metal ions after hydrolysis.PbS occurs on the hemimorphite surface after adding Pb2+ during sulfidization with Na2S,which is helpful to improve the adsorption of xanthate,and thus sulfidizing process is strengthened and the flotation recovery of hemimorphite is improved.

关键词

异极矿/硫化/金属离子/浮选/黄药

Key words

hemimorphite/sulfidization/metal ions/flotation/xanthate

分类

矿业与冶金

引用本文复制引用

张国范,张凤云..浮选过程中金属离子对异极矿硫化的影响[J].中南大学学报(自然科学版),2017,48(7):1689-1696,8.

基金项目

国家重点基础研究发展规划(973计划)项目(2014CB643402) (Project(2014CB643402) supported by the National Basic Research Development Program (973 Program) of China) (973计划)

中南大学学报(自然科学版)

OA北大核心CSCDCSTPCD

1672-7207

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