华中师范大学学报（自然科学版）2018，Vol.52Issue(1)：70-74,5.DOI:10.19603/j.cnki.1000-1190.2018.01.013
锌(Ⅱ)配合物超分子的合成、结构及性质研究
Synthesis, structure and properties of Zn(Ⅱ) supramolecular complex
摘要
Abstract
A new supramolecular complex [Zn (pydc) (Hpydc) (H2O) 2] · Him · H2O (1) was synthesized by hydrothermal method.The reaction was performed at 120℃ for two days,taking ZnF2 and pyridine-2,4-dicarboxylic acid as raw materials.The complex was characterized by X-ray single crystal diffraction,X-ray powder diffraction,infrared spectrum,thermal stability analysis and solid state fluorescence analysis at room temperature.The results show that the complex crystallizes in triclinic,space group P-1 with cell parameters:a=7.3791(6) (A),b=10.6071(8) (A),c=13.2907(10) (A),α=81.3620(10)°,β=77.4610(10)°,γ=79.5930(10)°;V=992.06(13) (A)3,Z=2.Solid state fluorescence at room temperature indicates that the complex exhibits blue fluorescence.关键词
锌配合物/蓝色荧光/超分子/晶体结构/吡啶2,4-二甲酸Key words
znic complexe/blue fluorescence/supramolecular/crystal structure/pyridine-2,4-dicarboxylic acid分类
化学化工引用本文复制引用
张万举,邹水香,李莲,汤雨朦,陈砚美..锌(Ⅱ)配合物超分子的合成、结构及性质研究[J].华中师范大学学报（自然科学版）,2018,52(1):70-74,5.基金项目
国家自然科学基金青年基金项目(21501061) （21501061）
湖北省自然科学基金项目(2016CFB147) （2016CFB147）
湖北省教育厅项目(D20172904) （D20172904）
黄冈师范学院化学实验教学示范中心项目(zj201723,zj201722,zx201724). （zj201723,zj201722,zx201724）
