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基于MX4结构的配位化合物析氢反应催化性能

姚会影 杨涛 黄幸 朱嘉 李青 徐伟 迟力峰

应用化学2018,Vol.35Issue(3):328-341,14.
应用化学2018,Vol.35Issue(3):328-341,14.DOI:10.11944/j.issn.1000-0518.2018.03.170453

基于MX4结构的配位化合物析氢反应催化性能

Coordination Complexes Based on MX4 Structure as Catalyst for Hydrogen Evolution Reaction

姚会影 1杨涛 2黄幸 3朱嘉 1李青 2徐伟 3迟力峰2

作者信息

  • 1. 北京师范大学化学学院理论与光化学教育部重点实验室 北京100875
  • 2. 苏州大学功能纳米与软物质研究院 江苏苏州215123
  • 3. 中国科学院化学研究所有机固体实验室 北京100190
  • 折叠

摘要

Abstract

The coordination complexes based on MX4(M =Fe,Co,Ni,Cu, et al, X =N,S,Se, et al.) structure have attracted a lot of attentions due to their novel structure and good electrocatalytic performance in hydrogen evolution reaction(HER).This review shows the recent research progresses of their catalytic properties for HER.The HER activities of MX4catalysts are affected by many factors, such as the metal center,coordination atoms,the ligand,the morphology and size of catalysts.Theoretical calculations are very helpful for understanding their influences on the activities of the catalysts and can further help us design more catalysts with higher activities.

关键词

催化析氢反应/配位化合物/MX4结构

Key words

catalytic hydrogen evolution reaction/coordination complex/MX4structure

分类

化学化工

引用本文复制引用

姚会影,杨涛,黄幸,朱嘉,李青,徐伟,迟力峰..基于MX4结构的配位化合物析氢反应催化性能[J].应用化学,2018,35(3):328-341,14.

基金项目

国家自然基金(21773016)资助Supported by the National Natural Science Foundation of China(No.21773016) (21773016)

应用化学

OA北大核心CSCDCSTPCD

1000-0518

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