应用化学2018,Vol.35Issue(3):328-341,14.DOI:10.11944/j.issn.1000-0518.2018.03.170453
基于MX4结构的配位化合物析氢反应催化性能
Coordination Complexes Based on MX4 Structure as Catalyst for Hydrogen Evolution Reaction
摘要
Abstract
The coordination complexes based on MX4(M =Fe,Co,Ni,Cu, et al, X =N,S,Se, et al.) structure have attracted a lot of attentions due to their novel structure and good electrocatalytic performance in hydrogen evolution reaction(HER).This review shows the recent research progresses of their catalytic properties for HER.The HER activities of MX4catalysts are affected by many factors, such as the metal center,coordination atoms,the ligand,the morphology and size of catalysts.Theoretical calculations are very helpful for understanding their influences on the activities of the catalysts and can further help us design more catalysts with higher activities.关键词
催化析氢反应/配位化合物/MX4结构Key words
catalytic hydrogen evolution reaction/coordination complex/MX4structure分类
化学化工引用本文复制引用
姚会影,杨涛,黄幸,朱嘉,李青,徐伟,迟力峰..基于MX4结构的配位化合物析氢反应催化性能[J].应用化学,2018,35(3):328-341,14.基金项目
国家自然基金(21773016)资助Supported by the National Natural Science Foundation of China(No.21773016) (21773016)