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海水电池用Mg-Ga-Hg合金在模拟深海环境下的性能

张月 徐海波 王东鹏 芦永红

电源技术2017,Vol.41Issue(12):1760-1763,4.
电源技术2017,Vol.41Issue(12):1760-1763,4.

海水电池用Mg-Ga-Hg合金在模拟深海环境下的性能

Performance of Mg-Ga-Hg alloy for seawater battery under simulated deep-sea environment

张月 1徐海波 1王东鹏 1芦永红1

作者信息

  • 1. 中国海洋大学化学化工学院海洋化学理论与工程技术教育部重点实验室,山东青岛266100
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摘要

Abstract

Mass loss measurement,open circuit potential (OCP) and galvanostatic discharge methods were used to assess the electrochemical performance of Mg-Ga-Hg alloy in its initial and intermittent periods under simulated deep-sea environment.The results show that the OCP of Mg-Ga-Hg alloy is lower than-1.95 V (vs.SCE) in 4 ℃ and 4 cm/s seawater,and at the discharge current density of 1-9 mA/cm2,its working potential can be kept at lower than-1.9 V (vs.SCE) with more than 50% current efficiency due to slow self-discharge rate.Meanwhile,Mg-Ga-Hg alloy can quickly start.Therefore,Mg-Ga-Hg alloy is a promising anode material for seawater battery to provide long-term power supply for observation instrument in deep sea.

关键词

Mg-Ga-Hg合金/海水电池/滞后电位/激活时间

Key words

Mg-Ga-Hg alloy/seawater battery/delayed potential/activation time

分类

信息技术与安全科学

引用本文复制引用

张月,徐海波,王东鹏,芦永红..海水电池用Mg-Ga-Hg合金在模拟深海环境下的性能[J].电源技术,2017,41(12):1760-1763,4.

基金项目

国家自然科学基金(21203172) (21203172)

国家自然科学基金重大仪器专项(41427803) (41427803)

山东省博士基金(BS2011NJ019) (BS2011NJ019)

山东省科技发展计划项目(2014GHY115036) (2014GHY115036)

电源技术

OA北大核心CSCDCSTPCD

1002-087X

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