分析测试学报2018，Vol.37Issue(2)：204-210,7.DOI:10.3969/j.issn.1004-4957.2018.02.009
β-环糊精功能化石墨烯修饰电极同时测定邻硝基苯酚与对硝基苯酚
Simultaneous Detection of o-Nitrophenol and p-Nitrophenol Using a β-Cyclodextrin Functionalized Graphene Modified Glassy Carbon Electrode
摘要
Abstract
A β-cyclodextrin functionalized graphene modified glassy carbon electrode (β-CD-GR/GCE) was prepared by drop-coating method.The electrochemical behaviors of o-nitrophenol (o-NP) and p-nitrophenol(p-NP) on the modified electrode were investigated by cyclic voltammetry and second-order derivative linear sweep voltammetry.The β-CD-GR/GCE showed an excellent electrocatalytical effect on the reduction of p-NP and o-NP.Besides,high resolution capacity to p-NP and oNP was obtained.Under the optimized conditions,second-order derivative linear sweep voltammetry was utilized for the determination of p-NP and o-NP.There were good linearities for o-NP and p-NP in the concentration ranges of 0.2-10 μmol/L and 0.06-10 μmoL/L with detection limits(S/N =3) of 0.08 μmol/L and 0.02 μmol/L,respectively.The proposed method could be applied in the simultaneous determination of o-NP and p-NP in environmental water samples with rapidness and accuracy.关键词
β-环糊精功能化石墨烯/修饰电极/邻硝基苯酚/对硝基苯酚/电化学行为/测定Key words
β-cyclodextrin functionalized graphene/modified electrode/o-nitrophenol/p-nitrophenol/electrochemical behavior/determination分类
化学化工引用本文复制引用
邓培红,梁姣丽,陈冬儿,蔡芬,黎秋燕,王婷..β-环糊精功能化石墨烯修饰电极同时测定邻硝基苯酚与对硝基苯酚[J].分析测试学报,2018,37(2):204-210,7.基金项目
湖南省自然科学基金资助项目(2016JJ4010) （2016JJ4010）
湖南省“光电信息技术”应用基础研究基地开放基金资助项目(GD16K02) （GD16K02）
绿色包装与生物纳米技术应用湖南省重点实验室对外开放基金资助项目(GPBN-2015-1) （GPBN-2015-1）
衡阳师范学院大学生课外学术科技作品竞赛重点项目(校科字[2017]号-8) （校科字[2017]号-8）
