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超临界CO2发泡阻燃聚苯乙烯研究

王亚桥 王文博 余科松 陈鹏 周洪福 王向东

中国塑料2017,Vol.31Issue(12):46-50,5.
中国塑料2017,Vol.31Issue(12):46-50,5.DOI:10.19491/j.issn.1001-9278.2017.12.008

超临界CO2发泡阻燃聚苯乙烯研究

Study on Flame Retardant Polystyrene Foamed by Supercritical Carbon Dioxide

王亚桥 1王文博 1余科松 1陈鹏 1周洪福 1王向东1

作者信息

  • 1. 北京工商大学材料与机械工程学院,北京100048
  • 折叠

摘要

Abstract

Polystyrene (PS) was modified with hexabromocyclododecane (HBCD) as a flame retardant and then was foamed by using supercritical CO2 as a foaming agent and hydrotalcite(HT) as a thermal stabilizer.The flame-retardant mechanism and foaming behavior of flame-retardant PS were studied.The results indicated that the thermal stability of HBCD could be improved by adding a proper amount of HT.However,the excessive amount of HT reduced the flame retardancy of PS.The thermal stability of HBCD was significantly influenced by the processing technologies and especially by shear flow field and processing temperature.The flame-retardant PS achieved a limiting oxygen index above 30 vol % through foaming with supercritical carbon dioxide.

关键词

六溴环十二烷/水滑石/热稳定性/阻燃/聚苯乙烯泡沫

Key words

hexabromocyclododecane/hydrotalcite/thermal stability/flame-retardant/polystyrene foam

分类

化学化工

引用本文复制引用

王亚桥,王文博,余科松,陈鹏,周洪福,王向东..超临界CO2发泡阻燃聚苯乙烯研究[J].中国塑料,2017,31(12):46-50,5.

基金项目

北京工商大学2017年研究生科研能力提升计划 ()

中国塑料

OA北大核心CSCDCSTPCD

1001-9278

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