中国塑料2017，Vol.31Issue(12)：94-100,7.DOI:10.19491/j.issn.1001-9278.2017.12.017
弹性光散射法研究正己烷溶液中SIS的自组装行为
Study on Self-assembly Behavior of SIS in N-hexane Solution by Elastic Light Scattering Method
许海锋1
作者信息
- 1. 东北林业大学理学院,黑龙江哈尔滨150040
- 折叠
摘要
Abstract
This paper reported an investigation on the self-assembly behavior of styrene-isoprene-styrene triblock copolymer(SIS) in an n-hexane solvent by an elastic light scattering method.The results indicated that the peak light scattering intensity showed a concave trend with a variation of temperature,and the effective grain diameter increased from 30.1 nm to 943.4 nm with a decrease of temperature.The molecular chains of SIS presented different aggregation states in the solution at different temperature.The light scattering signal was related to the aggregation of SIS and therefore can be used to analyze the phase separation mechanism of SIS.This article provides a new method for the study of phase separation mechanism of block polymers.关键词
弹性光散射法/自组装/相分离/嵌段聚合物Key words
elastic light scattering/self-assembly/phase separation/block polymer分类
化学化工引用本文复制引用
许海锋..弹性光散射法研究正己烷溶液中SIS的自组装行为[J].中国塑料,2017,31(12):94-100,7.
